Techโ—โ—โ—โ—โ—Difficulty 5 of 5

Are solid-state batteries the future, or just a promise?

Companies have promised the battery that swaps the liquid for a solid for years. Some work today in pacemakers; the car version keeps slipping.

โ–ถ Start the story

Solid-state batteries are both: a real technology already at work in small devices, and a promise for cars that has not yet been delivered. A solid-state battery uses a solid electrolyte to carry ions between the electrodes, instead of the liquid or gel in conventional batteries. In theory it offers much higher than typical lithium-ion batteries. Yet while many companies have promised at the gigawatt-hour scale in the 2020s, whether their batteries are ready is unknown.

Why the excitement? The solid electrolyte could act as an ideal separator that lets only lithium ions through, which might solve several problems of liquid-electrolyte lithium-ion batteries, including flammability, voltage range and mechanical strength. In theory, it would also mean more energy for the same weight.

Liquid electrolyte vs solid electrolyte

Conventional lithium-ion

  • Liquid or gel carries the ions
  • Flammable electrolyte
  • Proven, widely made
  • Lower in theory

Solid-state (promise)

  • Solid carries the ions
  • Potentially safer, denser
  • Cost and scale unsolved
  • and contact problems remain

The idea is old. Michael Faraday discovered solid electrolytes between 1831 and 1834. And such batteries are found today in and in RFID and wearable devices. The part not yet solved is the big one: making them cheap, durable and scalable enough for cars. To displace lithium-ion, they must overcome challenges in energy and power density, durability, material costs and chemical stability. One 2012 estimate put a single 20 amp-hour thin-film cell at US$100,000, and a high-range car would need 800 to 1,000 of them.

A long road for solid-state
  1. 1831โ€“34

    Faraday discovers solid electrolytes

  2. 2017

    Goodenough unveils a solid-state glass battery

  3. 2022

    JAXA reports solid-state batteries working on the ISS

  4. 2023

    Toyota says no commercial solid-state use before 2027

  5. 2023

    Panasonic announces a prototype it says charges 10โ€“80% in 3 minutes

Companies keep announcing dates, and the dates move. In June 2023 Toyota said it would not use commercial solid-state batteries until at least 2027. Each announcement is a promise to check, not a fact.

Quiz me

0/3

  1. 1.What is the basic difference between a solid-state battery and a conventional lithium-ion battery?
  2. 2.Why does a solid electrolyte not automatically make a lithium metal battery safe?
  3. 3.Which of these is a documented obstacle to solid-state batteries in cars?

Recap

Solid-state batteries are real but unfinished: cost, pressure, interface resistance and dendrites still stand between the lab and the car.

๐Ÿ’ก A trick to remember it ยท Swapping the liquid for a solid is like swapping soup for a brick: the brick cannot spill, but now you have to make sure it touches everything.

Surprising fact ยท Faraday discovered solid electrolytes in the 1830s, and such batteries already power pacemakers.

Sources (1)

No source, no claim. Every fact in this lesson (14 claims) cites at least one of these.

  1. [1]Solid-state battery ยท Wikipedia
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